TECHNICAL NOTES
Sep 1, 2000

As(III), As(V), Hg, and Pb Removal by Fe-Oxide Impregnated Activated Carbon

Publication: Journal of Environmental Engineering
Volume 126, Issue 9

Abstract

The removal of As(III), As(V), Hg(II), and Pb(II) by virgin and Fe(III) impregnated activated carbons (FeAC) was investigated. Iron-oxide impregnation increased the pHzpc of the carbon from 7.5 to about 8.2–8.7 but did not alter the surface area or the pore volume. The amount of acid or base needed to reach a given pH increased following impregnation, indicating that the FeAC was more active than its non-impregnated counterpart. Metal removal was a function of pH with removal increasing with pH for Hg(II) and Pb(II) and decreasing with pH for As(V). As(III) removal was not a strong function of pH below pH = 5, increased to a maximum at pH ≈ 7, then decreased with increasing pH. As(III) and As(V) removals were about one and two orders of magnitude higher, respectively, for the FeAC compared with the non-impregnated carbon, while Hg(II) and Pb(II) removals were only slightly higher. Fe-impregnation appears to be most effective for the anionic contaminants.

Get full access to this article

View all available purchase options and get full access to this article.

References

1.
Corapcioglu, M. O., and Huang, C. P. (1987). “The adsorption of heavy metals onto hydrous activated carbon.” Water Res., 9(9), 1031–1044.
2.
Dzombak, D.A., and Morel, F. M. M. (1990). Surface complexation modeling: Hydrous ferric oxide, Wiley, New York.
3.
Edwards, M. A., and Benjamin, M. M. (1989). “Adsorptive filtration using coated sand: a new treatment approach for treatment of metal-bearing wastes.” J. Water Pollution Control Fed., 61, 1523.
4.
Hsia, T. H. (1994). “Characterization of arsenate adsorption on hydrous iron oxide using chemical and physical methods.” Colloids and Surfaces A, 85, 1–7.
5.
Huang, C. P. ( 1981). “The surface acidity of hydrous solids.” Adsorption of inorganics at the solid-liquid interfaces, A. W. Anderson and A. J. Rubin, eds., Ann Arbor Science Publishers, Ann Arbor, Mich.
6.
James, R. O., and Healy, T. W. (1972). “Adsorption of hydrolyzable metal ions at the oxide-water interface. III: A thermodynamic model of adsorption.” J. Colloid and Interface Sci., 40(1), 65–81.
7.
Liu, J. C., and Huang, J. G. (1997). “Enhanced removal of As(V) from water with iron-coated spent catalyst.” Separation Sci. and Technol., 32(9), 1557–69.
8.
Manning, B. E., and Goldberg, S. (1997). “Adsorption and stability of arsenic(III) at the clay mineral-water interface.” Envir. Sci. and Technol., 31(7), 2005–2011.
9.
Reed, B. E. ( 1998). “Heavy metal-bearing wastewaters treatment using granular activated carbon columns (GAC).” Encyclopedia of environmental analyses and remediation, R. A. Meyers, ed., Wiley, New York, 5220–5248.
10.
Reed, B. E., Jamil, M., and Thomas, B. ( 1996). “Effect of pH, empty bed contact time (EBCT) and hydraulic loading (HLR) on Pb removal by granular activated carbon (GAC) columns.” Water Envir. Res., 68(5), 877.
11.
Reed, B. E., and Matsumoto, M. R. ( 1991). “Modeling surface acidity of two powdered activated carbons: Comparison of diprotic and monoprotic surface representations.” Carbon, 29(8), 1191.
12.
Standard methods for the examination of water and wastewater. (1992). American Public Health Association, Washington, D.C.
13.
U.S. Environmental Protection Agency (USEPA). (1996). “ICR manual for bench- and pilot-scale treatment studies.” EPA814-B-96-003, Office of Water, Washington, D.C.
14.
Westall, J. C., Zachery, J. L., and Morel, F. M. M. (1976). “Mineql: A computer program for the calculation of chemical equilibrium composition of aqueous systems.” Tech. Note No. 18, Ralph M. Parsons Lab., Massachusetts Institute of Technology, Cambridge, Mass.
15.
Yates, D. E., and Healy, T. R. (1975). “Mechanisms of anion adsorption at the ferric and chromic oxide/water interface.” J. Colloid and Interface Sci., 52(2), 222–228.

Information & Authors

Information

Published In

Go to Journal of Environmental Engineering
Journal of Environmental Engineering
Volume 126Issue 9September 2000
Pages: 869 - 873

History

Received: Jun 24, 1998
Published online: Sep 1, 2000
Published in print: Sep 2000

Permissions

Request permissions for this article.

Authors

Affiliations

Member, ASCE
Assoc. Prof., Dept. of Civ. and Envir. Engrg., Univ. of Missouri-Columbia, Columbia, MO 65211-2200.
PhD Candidate, Dept. of Civ. and Envir. Engrg., Univ. of Missouri-Columbia, Columbia, MO.
Envir. Engr., Roy F. Westin, Inc.; formerly, Grad. Student, Dept. of Civ. and Envir. Engrg., West Virginia Univ., Morgantown, WV.

Metrics & Citations

Metrics

Citations

Download citation

If you have the appropriate software installed, you can download article citation data to the citation manager of your choice. Simply select your manager software from the list below and click Download.

Cited by

View Options

Get Access

Access content

Please select your options to get access

Log in/Register Log in via your institution (Shibboleth)
ASCE Members: Please log in to see member pricing

Purchase

Save for later Information on ASCE Library Cards
ASCE Library Cards let you download journal articles, proceedings papers, and available book chapters across the entire ASCE Library platform. ASCE Library Cards remain active for 24 months or until all downloads are used. Note: This content will be debited as one download at time of checkout.

Terms of Use: ASCE Library Cards are for individual, personal use only. Reselling, republishing, or forwarding the materials to libraries or reading rooms is prohibited.
ASCE Library Card (5 downloads)
$105.00
Add to cart
ASCE Library Card (20 downloads)
$280.00
Add to cart
Buy Single Article
$35.00
Add to cart

Get Access

Access content

Please select your options to get access

Log in/Register Log in via your institution (Shibboleth)
ASCE Members: Please log in to see member pricing

Purchase

Save for later Information on ASCE Library Cards
ASCE Library Cards let you download journal articles, proceedings papers, and available book chapters across the entire ASCE Library platform. ASCE Library Cards remain active for 24 months or until all downloads are used. Note: This content will be debited as one download at time of checkout.

Terms of Use: ASCE Library Cards are for individual, personal use only. Reselling, republishing, or forwarding the materials to libraries or reading rooms is prohibited.
ASCE Library Card (5 downloads)
$105.00
Add to cart
ASCE Library Card (20 downloads)
$280.00
Add to cart
Buy Single Article
$35.00
Add to cart

Media

Figures

Other

Tables

Share

Share

Copy the content Link

Share with email

Email a colleague

Share