Heat and Mass Transfer during Microwave Steam Treatment of Contaminated Soils
Publication: Journal of Environmental Engineering
Volume 126, Issue 12
Abstract
A time-dependent mechanistic model has been developed to describe the coupled heat and mass transfer during microwave steam treatment of contaminated soils. The model consists of multiphase mass and energy conservation equations, along with various temperature-dependent parameterizations of important physical state properties. The coupled nonlinear equations were solved numerically by applying a macroscopic control volume method with the appropriate boundary and initial conditions and using a finite-difference scheme. Microwave heating experiments of soil samples were performed. The effects of microwave power, soil sample depth, and soil type on water evaporation rate and temperature were measured with time. The modeled results are in good agreement with the experimental data. The results revealed that microwave power density and soil sample depth significantly affect the microwave evaporation process of water from soils. Water evaporation rate and temperature variation are complex and associated with the dielectric properties of liquid water distributed within the soil. The deeper the soil sample, the more nonuniform the evaporation process, although nonuniformities diminish as the evaporation process approaches completion. Finally it was verified that soil types and their thermal properties play a minor role, provided that the soil minerals are microwave transparent.
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References
1.
Amend, L. J., and Lederman, P. B. ( 1992). “Critical evaluation of PCB remediation technologies.” Envir. Progress, 11(3), 173–177.
2.
Chang, D. P. Y. ( 1998). “Steam treatment of soil—A case study of outreach.” Envir. Health Perspectives—Supplement, 106(4), 1065–1067.
3.
Chang, D. P. Y., Di, P., Hutchinson, M., Udell, K. S., and Itamura, M. ( 1997). “Feasibility of steam treatment of PCB-contaminated soil.” Proc., 1997 Int. Conf. of Incineration and Thermal Treatment Technol., 811–816.
4.
Chen, S., and Whitaker, S. ( 1986). “Moisture distribution during the constant rate drying period for unconsolidated porous media: Failure of the diffusion theory.” Drying 86, A. S. Mujumdar, ed., Vol. 1, Hemisphere Publication Corp., New York, 39–48.
5.
Itamura, M. T., and Udell, K. S. ( 1995). “An analysis of optimal cycling time and ultimate chlorinated hydrocarbon removal from heterogeneous media using cycle steam injection.” Proc., ASME Heat Transfer and Fluid Engrg. Div., Vol. 1, 651–660.
6.
Luikov, A. V. ( 1966). Heat and mass transfer in capillary porous bodies, Pergamon, Oxford, U.K.
7.
Marshall, S. ( 1991). Handbook of toxic and hazardous chemical and carcinogens, 3rd Ed., Noyes Publication, Park Ridge, N.J.
8.
Moran, M. J., and Shapiro, H. N. ( 1992). Fundamentals of engineering thermodynamics, 2nd Ed., Wiley, New York.
9.
Patankar, S. V. ( 1980). Numerical heat transfer and fluid flow, McGraw-Hill, New York.
10.
Perry, R. H., and Chilton, C. H. ( 1973). Chemical engineer's handbook, 5th Ed., McGraw-Hill, New York.
11.
U.S. Environmental Protection Agency (USEPA). ( 1993). “Technology alternatives for the remediation of PCB-contaminated soils and sediment.” EPA/540/S-93-506, Washington, D.C.
12.
van Genuchten, M. Th. ( 1980). “Closed-form equation for predicting the hydraulic conductivity of unsaturated soils.” Soil Sci. Soc. Am. Proc., 44(5), 892–898.
13.
Von Hippel, A. R. ( 1954). Dielectrics and waves, MIT Press, Cambridge, Mass.
14.
Wei, C. K., Davis, H. T., Davis, E. A., and Gordon, J. ( 1985). “Heat and mass transfer in water-laden sandstone: Microwave heating.” AIChE J., 31(5), 842–848.
15.
Whitaker, S. ( 1977). “A theory of drying in porous media.” Advances in heat transfer, Vol. 13, 119–203.
16.
Whitaker, S., and Chou, W. T.-H. ( 1983). “Drying granular porous media—Theory and experiment.” Drying Technol., 1(1), 3–33.
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Received: Nov 23, 1999
Published online: Dec 1, 2000
Published in print: Dec 2000
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