TECHNICAL PAPERS
Dec 1, 2000

Effect of pH and VFA on Hydrolysis of Organic Solid Waste

Publication: Journal of Environmental Engineering
Volume 126, Issue 12

Abstract

The anaerobic hydrolysis rate of organic solid waste was studied at fixed volatile fatty acid (VFA) concentrations ranging from 3 to 30 g COD/L and fixed pH values between 5 and 7. For separate control of both VFA and pH, a special completely mixed reactor was designed. In this way, it was possible to distinguish between the inhibitory effects of pH, total VFA, and undissociated VFA on anaerobic hydrolysis. It was shown that hydrolysis of the organic solid waste followed first-order kinetics. Using a statistical analysis, it was found that the hydrolysis rate constant was pH dependent but was not related to the total VFA and undissociated VFA concentrations.

Get full access to this article

View all available purchase options and get full access to this article.

References

1.
American Public Health Association (APHA), American Water Works Association (AWWA), and Water Pollution Control Federation (WPCF). ( 1985). Standard methods for the examination of water and wastewater, 16th Ed., APHA, Washington, D.C.
2.
Arntz, H.-J., Stoppok, E., and Buchholz, K. ( 1985). “Anaerobic hydrolysis of beet pulp—Discontinuous experiments.” Biotechnol. Lett., 7, 113–118.
3.
Chen, Y. R., and Hashimoto, A. G. ( 1980). “Substrate utilization kinetic model for biological treatment process.” Biotechnology Bioengineering, 22, 2081–2095.
4.
de Baere, L., Verdonck, O., and Verstraete, W. ( 1985). “High rate dry anaerobic composting process for the organic fraction of solid wastes.” Proc., 7th Symp. on Biotechnology for Fuels and Chemicals, C. D. Scott, ed., Wiley, London, 321–330.
5.
Eastman, J. A., and Ferguson, J. F. ( 1981). “Solubilization of particulate organic carbon during the acid phase of anaerobic digestion.” J. Water Pollution Control Fed., 53, 352–366.
6.
Ghosh, S., and Klass, D. L. ( 1978). “Two phase anaerobic digestion.” Process Biochem., 13, 15–24.
7.
Grobicki, A., and Stuckey, D. C. ( 1992). “Hydrodynamic characteristics of the anaerobic baffled reactor.” Water Res., 26, 371–378.
8.
Gujer, W., and Zehnder, A. J. B. ( 1983). “Conversion processes in anaerobic digestion.” Water Sci. and Technol., 15, 127–167.
9.
Hobson, P. N. ( 1983). “The kinetics of anaerobic digestion of farm wastes.” J. Chem. Tech. Biotechnol., 33B, 1–20.
10.
Levenspiel, O. ( 1972). Chemical reaction engineering, 2nd Ed., Wiley, New York.
11.
Lin, G.-Y. ( 1991). “Anaerobic digestion of landfill leachate.” Water SA, 17, 301–306.
12.
Llabrés-Luengo, P., and Mata-Alvarez, J. ( 1988). “The hydrolytic step in a dry digestion system.” Biol. Wastes, 23, 25–37.
13.
Mata-Alvarez, J. ( 1987). “A dynamic simulation of a two-phase anaerobic digestion system for solid wastes.” Biotechnology Bioengineering, 30, 844–851.
14.
Noike, T., Endo, G., Chang, J. E., Yaduchi, J. I., and Matsumoto, J. I. ( 1985). “Characteristics of carbohydrate degradation and the rate-limiting step in anaerobic digestion.” Biotechnology Bioengineering, 27, 1482–1489.
15.
Roosmalen, G. R. E. M. van, and Langerijt, J. C. van de. ( 1989). “Green waste composting in The Netherlands.” Biocycle, 30, 32–35.
16.
ten Brummeler, E., Horbach, H. C. J. M., and Koster, I. W. ( 1991). “Dry anaerobic batch digestion of the organic fraction of municipal solid waste.” J. Chem. Tech. Biotechnol., 50, 191–209.
17.
Vavilin, V. A., Rytov, S. V., and Lokshina, L. Ya. ( 1996). “A description of hydrolysis kinetics in anaerobic degradation of particulate organic matter.” Biores. Technol., 56, 229–237.
18.
Veeken, A. ( 1998). “Removal of heavy metals from biowaste.” PhD thesis, Wageningen Agriculture University, Wageningen, The Netherlands.
19.
Veeken, A., and Hamelers, B. ( 1999). “Effect of temperature on hydrolysis rate of selected biowise components.” Biores. Technol., 69, 249–254.
20.
Veeken, A., and Hamelers, B. ( 2000). “Effect of substrate-seed mixing and leachate recirculation on solid state digestion of biowaste.” Water Sci. and Technol.
21.
Weltz, B. ( 1985). Atomic absorption spectroscopy, VCH, Weinheim.
22.
White, P. R., Franke, M., and Hindle, P. ( 1995). Integrated solid waste management: A lifecycle inventory, Blackie Academic & Professional, London.
23.
Zoetemeyer, R. J. ( 1982). “Acidogenesis of soluble carbohydrate containing waste water.” PhD thesis, University of Amsterdam, Amsterdam.

Information & Authors

Information

Published In

Go to Journal of Environmental Engineering
Journal of Environmental Engineering
Volume 126Issue 12December 2000
Pages: 1076 - 1081

History

Received: Apr 9, 1999
Published online: Dec 1, 2000
Published in print: Dec 2000

Permissions

Request permissions for this article.

Authors

Affiliations

Sr. Res., Dept. of Envir. Technol., Agriculture Univ., 6700 EV Wageningen, The Netherlands.
Sr. Res., Dept. of Chem. Enzymology, Moscow State Univ., 119899 Moscow, Russia.
Mgr., Emission Control, Afvalzorg Deponie BV, Haarlem, The Netherlands.
Asst. Prof., Dept. Envir. Technol., Agriculture Univ., 6700 EV Wageningen, The Netherlands.

Metrics & Citations

Metrics

Citations

Download citation

If you have the appropriate software installed, you can download article citation data to the citation manager of your choice. Simply select your manager software from the list below and click Download.

Cited by

View Options

Get Access

Access content

Please select your options to get access

Log in/Register Log in via your institution (Shibboleth)
ASCE Members: Please log in to see member pricing

Purchase

Save for later Information on ASCE Library Cards
ASCE Library Cards let you download journal articles, proceedings papers, and available book chapters across the entire ASCE Library platform. ASCE Library Cards remain active for 24 months or until all downloads are used. Note: This content will be debited as one download at time of checkout.

Terms of Use: ASCE Library Cards are for individual, personal use only. Reselling, republishing, or forwarding the materials to libraries or reading rooms is prohibited.
ASCE Library Card (5 downloads)
$105.00
Add to cart
ASCE Library Card (20 downloads)
$280.00
Add to cart
Buy Single Article
$35.00
Add to cart

Get Access

Access content

Please select your options to get access

Log in/Register Log in via your institution (Shibboleth)
ASCE Members: Please log in to see member pricing

Purchase

Save for later Information on ASCE Library Cards
ASCE Library Cards let you download journal articles, proceedings papers, and available book chapters across the entire ASCE Library platform. ASCE Library Cards remain active for 24 months or until all downloads are used. Note: This content will be debited as one download at time of checkout.

Terms of Use: ASCE Library Cards are for individual, personal use only. Reselling, republishing, or forwarding the materials to libraries or reading rooms is prohibited.
ASCE Library Card (5 downloads)
$105.00
Add to cart
ASCE Library Card (20 downloads)
$280.00
Add to cart
Buy Single Article
$35.00
Add to cart

Media

Figures

Other

Tables

Share

Share

Copy the content Link

Share with email

Email a colleague

Share