TECHNICAL PAPERS
Nov 1, 2000

Method for Attenuation of White Phosphorus Contamination in Wetlands

Publication: Journal of Environmental Engineering
Volume 126, Issue 11

Abstract

White phosphorus, a manufactured form of elemental phosphorus, is both toxic and persistent in saturated environments. This form of phosphorus (P4) is used by militaries worldwide as a component for obscurants, tracer rounds, and incendiary munitions. At Eagle River Flats, an estuarine salt marsh located on Fort Richardson, Alaska, white phosphorus has been directly linked through carcass analysis to the deaths of thousands of dabbling waterfowl. Particulate residue from ordnance contaminates the permanently ponded areas of Eagle River Flats, where the waterfowl sieve the soft bottom sediments for food items, picking up P4 particles in the process. Death follows within hours. Large-scale investigations into the nature, extent, and persistence of the contaminant were initiated in 1989, followed 4 years later by work on the testing and analysis of remediation methods. In 1997, a method for in situ remediation of the contaminant through low-impact pumping and draining of ponded areas to enhance natural attenuation of white phosphorus was tested. Results indicate that pond pumping is a very effective remediation technique.

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References

1.
Blumbergs, P., Gillmann, R. C., Gault, R., Hatto, D. L., Ash, A. B., and Stevens, C. L. ( 1973). “Chemical process studies for commercially unavailable materials.” Edgewood Arsenal Contract Rep. 1510-2, Edgewood Arsenal, Aberdeen Proving Ground, Md.
2.
Bouwkamp, C. A. ( 1995). “Evaluation of white phosphorus effects on the aquatic ecosystem, Eagle River Flats, Fort Richardson, Alaska.” Interagency expanded site investigation: Evaluation of white phosphorus contamination and potential treatability at Eagle River Flats, Alaska, FY 94 Final Rep., CRREL Contract Rep. to the U.S. Army Alaska, Directorate of Public Works, C. H. Racine and D. Cate, eds., U.S. Army Cold Regions Research and Engineering Laboratory, Hanover, N.H., 335–402.
3.
CH2M Hill. ( 1998). “Record of decision for Operable Unit C, Fort Richardson, Anchorage, Alaska.” Contract No. DAC85-95-D-0015, Delivery Order 12, CH2M Hill, Anchorage, Alaska.
4.
Collins, C. M. ( 1994). “Pond draining treatability study.” Interagency expanded site investigation: Evaluation of white phosphorus contamination and potential treatability at Eagle River Flats, Alaska, FY 93 Final Rep., CRREL Contract Rep. to the U.S. Army Alaska, Directorate of Public Works, C. H. Racine and D. Cate, eds., Hanover, N.H., 323–332.
5.
Dainton, F. S., and Bevington, J. C. ( 1946). “The oxidation and inflammation of yellow phosphorus.” Trans. Faraday Soc., London, 42, 377–389.
6.
Idler, D. R. ( 1969). “Coexistence of a fishery and a major industry in Placentia Bay.” Chem. in Can., Ottawa, Canada, 21, 16–21.
7.
Lawson, D. E., Hunter, L. E., Bigl, S. R., Nadeau, B. M., Wyrick, P. B., and Bodette, J. H. ( 1996). “Physical system dynamics and white phosphorus fate and transport, 1994. Eagle River Flats, Fort Richardson, Alaska.” CRREL Rep. CR 96-9, U. S. Army Cold Regions Research and Engineering Laboratory, Hanover, N.H.
8.
Mellor, J. W. ( 1928). A comprehensive treatise on inorganic and theoretical chemistry, Vol. 8, Longman's, Green, and Co., London.
9.
Pochop, P. A., Cummings, J. L., Yoder, C. A., and Gossweiler, W. A. (2000). “A physical barrier to reduce WP mortalities of foraging waterfowl.”J. Envir. Engrg. ASCE, 126(2), 182–187.
10.
Racine, C. H., et al. ( 1992). “White phosphorus poisoning of waterfowl in an Alaskan salt marsh.” J. Wildlife Diseases, 28(4), 669–673.
11.
Racine, C. H., Chacho, E. F., Tracy, B., and Berger, P. ( 1999). “Monitoring physical and biological changes in Eagle River Flats.” Interagency expanded site investigation: Evaluation of white phosphorus contamination and potential treatability at Eagle River Flats, Alaska, FY 98 Final Rep., CRREL Contract Rep. to the U.S. Army Alaska, Directorate of Public Works, C. M. Collins and M. J. Hardenberg, eds., Hanover, N.H., 109–120.
12.
Roebuck, B. D., Nam, S. I., MacMillan, D. L., Baumgarten, K. J., and Walsh, M. E. ( 1998). “Toxicology of white phosphorus (P4) to ducks and risk for their predators: Effect of particle size.” Envir. Toxicology and Chem., 17(3), 511–518.
13.
Roebuck, B. D., Walsh, M. E., Racine, C. H., Reitsma, L. R., Steele, B. B., and Nam, S. I. ( 1994). “Predation of ducks poisoned by white phosphorus: Exposure and risk to predators.” Envir. Toxicology and Chem., 13(10), 1613–1618.
14.
Spanggord, R. J., et al. ( 1985). “Environmental fate of white phosphorus/felt and red phosphorus butyl rubber military screening smokes.” Rep. No. ADA176922, SRI International, Menlo Park, Calif.
15.
Sparling, D. W., Gustafson, M., Klein, P., and Karouna-Renier, N. ( 1997). “Toxicity of white-phosphorus to waterfowl: Acute exposure to mallards.” J. Wildlife Diseases, 32(2), 187–197.
16.
Stich, C. ( 1953). “Solubility of phosphorus.” Pharmazie, Berlin, 8, 202.
17.
U.S. Environmental Protection Agency (USEPA). ( 1995). “Method 7580: White phosphorus (P4) by solvent extraction and gas chromatography.” Test methods for evaluating solid waste, physical/chemical methods (SW-846), Update III, Office of Solid Waste, Washington, D.C., 7580-1–7580-20.
18.
Walsh, M. E. ( 1993). “White phosphorus: An environmental contaminant.” MS thesis, Thayer School of Engrg., Dartmouth College, Hanover, N.H.
19.
Walsh, M. E. ( 1995). “Analytical method for white phosphorus in water.” Bull. of Envir. Contamination and Toxicology, 54(3), 432–439.
20.
Walsh, M. E., and Collins, C. M. ( 1993). “Distribution of white phosphorus residues from the detonation of 81-mm mortar WP-smoke rounds at an upland site.” CRREL Rep. SR 93-18, U.S. Army Cold Regions Research and Engineering Laboratory, Hanover, N.H.
21.
Walsh, M. E., Collins, C. M., Bailey, R. N., and Grant, C. L. ( 1997). “Composite sampling of sediments contaminated with white phosphorus.” CRREL Rep. SR 97-30, U.S. Army Cold Regions Research and Engineering Laboratory, Hanover, N.H.
22.
Walsh, M. E., Collins, C. M., and Racine, C. H. ( 1996). “Persistence of white phosphorus (P4) particles in salt marsh sediments.” Envir. Toxicology and Chem., 15(6), 846–855.
23.
Walsh, M. E., Racine, C. R., Collins, C. M., Bouwkamp, C., and Thorne, P. T. ( 1995). “Simple field screening method for white phosphorus (P4) in sediment.” CRREL Rep. SR 95-25, U.S. Army Cold Regions Research and Engineering Laboratory, Hanover, N.H.
24.
Walsh, M. E., and Taylor, S. ( 1993). “Analytical method for white phosphorus residues in munitions-contaminated sediments.” Analytica Chemica Acta, Amsterdam, The Netherlands, 282(1), 55–61.
25.
Walsh, M. R., and Collins, C. M. ( 1998). “Dredging as remediation for white phosphorus contamination at Eagle River Flats, Alaska.” CRREL Rep. CR 98-5, U.S. Army Cold Regions Research and Engineering Laboratory, Hanover, N.H.
26.
Walsh, M. R., Walsh, M. E., and Collins, C. M. ( 1999a). “Enhanced natural remediation of white-phosphorus-contaminated wetlands through controlled pond draining.” CRREL Rep. CR 99-10, U.S. Army Cold Regions Research and Engineering Laboratory, Hanover, N.H.
27.
Walsh, M. R., Walsh, M. E., and Collins, C. M. ( 1999b). “Remediation methods for white phosphorus contamination in a coastal wetland.” Environmental Conservation, Cambridge, U.K., 26(2), 112–124.

Information & Authors

Information

Published In

Go to Journal of Environmental Engineering
Journal of Environmental Engineering
Volume 126Issue 11November 2000
Pages: 1013 - 1018

History

Received: Feb 3, 2000
Published online: Nov 1, 2000
Published in print: Nov 2000

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Authors

Affiliations

Michael R. Walsh, P.E.
Mech. Engr., U.S. Army Engr., Res. and Devel. Ctr., Cold Regions Res. and Engrg. Lab., Hanover, N.H. 03755.
Chemical Engr., U.S. Army Engr. Res. and Devel. Ctr., Cold Regions Res. and Engrg. Lab., Hanover, N.H.
Res. Phys. Sci., U.S. Army Engr. Res. and Devel. Ctr., Cold Regions Res. and Engrg. Lab., Fairbanks, AK 99703.

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