TECHNICAL PAPERS
Jul 1, 1999

Single-Sludge Nitrogen Removal Model: Calibration and Verification

Publication: Journal of Environmental Engineering
Volume 125, Issue 7

Abstract

The objective of this work was to calibrate and verify a modified version of a mathematical model of a single-sludge system for nitrification and denitrification. The new model is based on long-term experimental results, and the main modifications are related to the biological oxygen demand removal kinetics and biomass activity expressions. The model consists of 22 equations with 54 parameters, including 19 kinetic and stoichiometric coefficients. Experiments were performed on four bench-scale units and one pilot plant fed with domestic wastewater. Six sets of runs were carried out under different operational conditions. In the calibration procedure, a mathematical algorithm was implemented, in which an optimal set of coefficients was selected. Several coefficients were directly determined experimentally. Model verification was based on the comparison of experimental results with the values predicted by the mathematical model using a fixed set of model coefficients for each set of runs. From the verification results, the model is considered to be a useful one for the design of a new treatment system and operation of an existing one.

Get full access to this article

View all available purchase options and get full access to this article.

References

1.
Argaman, Y. (1991). “Chemical reaction engineering and activated sludge—A research no.” Water Res., 25(12), 1583–1586.
2.
Argaman, Y. (1995). “A steady-state model for the single-sludge activated sludge system. 1. Model description.” Water Res., 29(1), 137–145.
3.
Argaman, Y., Eckenfelder, W. W. Jr., and O'Reilly, A. J. (1998). “Applicability of batch tests data for industrial wastewater continuous flow process design.” WEFTEC'98, Vol. 3, 453–461.
4.
Chai Sung Gee, Pfeffer, J. T., and Suidan, M. T. (1990). “Nitrosomonas and nitrobacter interactions in biological nitrification.”J. Envir. Engrg., ASCE, 116(1), 4–17.
5.
Daigger, G. T., and Grady, C. P. L. Jr. (1995). “The use of models in biological process design.” 68th Annu. Conf., Water Environment Federation, Alexandria, Va.
6.
Drtil, M., Nemeth, P., and Bodik, I. (1993). “Kinetic constants of nitrification.” Water Res., 27(1), 35–39.
7.
Eckenfelder, W. W. Jr. (1990). “Estimating oxygen requirements and waste sludge from activated sludge with and without primary clarifiers treating municipal wastewater.” Envir. Technol., 11(5), 793–798.
8.
Ekama, G. A., Dold, P. L., and Marais, G. V. R. (1986). “Procedures for determining influent COD fractions and the maximum specific growth rate of heterotrophs in activated sludge system.” Water Sci. and Technol., 18(6), 91–114.
9.
Grau, P., Dohanyos, M., and Chudoba, J. (1975). “Kinetics of multi-component substrate removal by activated sludge.” Water Res., 9(7), 637–642.
10.
Gujer, W., Henze, M., Mino, T., Matsuo, T., Wentzel, M. C., and Marais, G. V. R. (1995). “The activated sludge model no. 2: Biological phosphorus removal.” Water Sci. and Technol., 31(2), 1–11.
11.
Hanaki, K., Wantawin, C., and Ohgaki, S. (1990). “Effects of the activity of heterotrophs on nitrification in a suspended-growth reactor.” Water Res., 24(3), 289–296.
12.
Henze, M. (1986). “Nitrate versus oxygen utilization rates determination.” Water Sci. and Technol., 18(6), 115–122.
13.
Kappeler, J., and Gujer, W. (1992). “Estimation of kinetic parameters of heterotrophic biomass under aerobic conditions and characterization of wastewater for activated sludge modeling.” Water Sci. and Technol., 25(6), 125–139.
14.
Knowless, G., Downing, A. L., and Barrett, M. J. (1965). “Determination of kinetic constants for nitrifying bacteria in mixed culture, with the aid of an electronic computer.” J. Gen. Microbiol., 38(2), 208–219.
15.
Kroiss, H., and Ruider, E. (1977). “Comparison of the plug-flow and completely mixed activated sludge process.” Progress in Water Technol., 8(6), 169–173.
16.
Metcalf and Eddy. (1991). Wastewater engineering treatment, disposal and reuse, 3rd Ed., McGraw-Hill, New York.
17.
Nitrogen control. (1993). EPA/625/R-93/010. U.S. Environmental Protection Agency, Washington, D.C.
18.
PEST. (1997). “Parameter estimation.” http://www.0zemail.com.au/%7Ewcomp/pcstsoft.html
19.
Quirk, T. P., and Eckenfelder, W. W. Jr. (1986). “Active biomass in activated sludge analysis and design.” J. WPCF, 58(9), 932–936.
20.
Standard methods for the examination of water and wastewater, 19th Ed. (1996). American Public Health Association, American Water Works Association, and Water Pollution Control Federation, Washington, D.C.
21.
Stenstrom, M. K., and Song, S. S. (1991). “Effect of oxygen transport limitation on nitrification in the activated sludge process.” J. WPCF, 63(3), 208–219.
22.
Tischler, L. F., and Eckenfelder, W. W. Jr. (1969). “Linear substrate removal in the activated sludge process.” Advances in water pollution research. Pergamon, Tarrytown, N.Y.
23.
van Niekerk, A., Jenkins, D., and Richard, M. G. (1987). “Application of batch kinetic data to the sizing of continuous flow activated sludge reactors.” Water Sci. and Technol., 19(3/4), 505–516.
24.
Williamson, K., and McCarty, P. L. (1975). “Rapid measurement of Monod half-velocity coefficients for bacterial kinetics.” Biotechnol. Bioengrg., 17(6), 915–924.
25.
Wolfbauer, O., Klettner, H., and Moser, F. (1978). “Reaction engineering models of biological waste water treatment and the kinetics of the activated sludge process.” Chemical Engrg. Sci., 33(8), 953–960.

Information & Authors

Information

Published In

Go to Journal of Environmental Engineering
Journal of Environmental Engineering
Volume 125Issue 7July 1999
Pages: 608 - 617

History

Received: Jun 12, 1998
Published online: Jul 1, 1999
Published in print: Jul 1999

Permissions

Request permissions for this article.

Authors

Affiliations

Prof., Milstone/St. Louis Chair of Envir. Engrg., Technion–Israel Inst. of Technol., Haifa 32000, Israel.
PhD Engr., Envir. and Water Res. Engrg., Technion–Israel Inst. of Technol., Haifa 32000, Israel.
DSc Engr., TAHAL Consulting Engineers, Ltd., 54 Even Gvirol, Tel-Aviv 64364, Israel.
PhD Engr., Israel Ministry of Environment, Jerusalem 95464, Israel.

Metrics & Citations

Metrics

Citations

Download citation

If you have the appropriate software installed, you can download article citation data to the citation manager of your choice. Simply select your manager software from the list below and click Download.

Cited by

View Options

Get Access

Access content

Please select your options to get access

Log in/Register Log in via your institution (Shibboleth)
ASCE Members: Please log in to see member pricing

Purchase

Save for later Information on ASCE Library Cards
ASCE Library Cards let you download journal articles, proceedings papers, and available book chapters across the entire ASCE Library platform. ASCE Library Cards remain active for 24 months or until all downloads are used. Note: This content will be debited as one download at time of checkout.

Terms of Use: ASCE Library Cards are for individual, personal use only. Reselling, republishing, or forwarding the materials to libraries or reading rooms is prohibited.
ASCE Library Card (5 downloads)
$105.00
Add to cart
ASCE Library Card (20 downloads)
$280.00
Add to cart
Buy Single Article
$35.00
Add to cart

Get Access

Access content

Please select your options to get access

Log in/Register Log in via your institution (Shibboleth)
ASCE Members: Please log in to see member pricing

Purchase

Save for later Information on ASCE Library Cards
ASCE Library Cards let you download journal articles, proceedings papers, and available book chapters across the entire ASCE Library platform. ASCE Library Cards remain active for 24 months or until all downloads are used. Note: This content will be debited as one download at time of checkout.

Terms of Use: ASCE Library Cards are for individual, personal use only. Reselling, republishing, or forwarding the materials to libraries or reading rooms is prohibited.
ASCE Library Card (5 downloads)
$105.00
Add to cart
ASCE Library Card (20 downloads)
$280.00
Add to cart
Buy Single Article
$35.00
Add to cart

Media

Figures

Other

Tables

Share

Share

Copy the content Link

Share with email

Email a colleague

Share