TECHNICAL PAPERS
Jun 1, 1997

Determination of Transfer Rate Constants and Partition Coefficients for Air Phase Biofilters

Publication: Journal of Environmental Engineering
Volume 123, Issue 6

Abstract

The determination of transfer rate constants (k) and concentration partition coefficients (kh) is required for biofilter mathematical models. A bench-scale technique was developed and used to evaluate k and kh values for four different packing materials: (1) compost; (2) a mixture of compost and diatomaceous earth (DE); (3) Calgon granular activated carbon (GAC); and (4) Westates GAC. Two vapor phase contaminants were used: ethanol and carbon dioxide. Experimental results showed that this technique produced estimated kh values that were similar to both “batch” and “spike test” results, indicating the accuracy of the procedure. Calculated kh values for carbon dioxide were two orders of magnitude less than those for ethanol. The water content of the packing material strongly affects kh values. High water content increased kh values for ethanol and decreased kh values for carbon dioxide.

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References

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Brusseau, M. L.(1991). “Transport of organic chemicals by gas advection in structured or heterogeneous porous media: development of a model and application to column experiments.”Water Resour. Res., 27(12), 3189–3199.
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Hodge, D. S., and Devinny, J.(1995). “Modeling removal of air contaminants by biofiltration.”J. Envir. Engrg., ASCE, 121(1), 21–44.
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Hodge, D. S., Medina, V., Wang, Y., and Devinny, J. (1992). “Biofiltration: application for VOC emissions control.”Rep. Presented at the 47th Annu. Purdue Industrial Waste Conf., Lewis Publishers, Boca Raton, Fla.
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Go to Journal of Environmental Engineering
Journal of Environmental Engineering
Volume 123Issue 6June 1997
Pages: 577 - 585

History

Published online: Jun 1, 1997
Published in print: Jun 1997

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Authors

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Douglas S. Hodge
Dir. of Bioremediation Services, The Reynolds Group, 250 El Camino Real, Ste. 214, Tustin, CA 92680.
Joseph S. Devinny
Prof., Dept. of Civ. Engrg., Univ. of Southern California, Los Angeles, CA 90089-2531.

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