Risk Variability Due to Uniform Soil Remediation Goals
Publication: Journal of Environmental Engineering
Volume 122, Issue 7
Abstract
If a single contaminant concentration in soil were to be used as the remediation goal at all potential remediation sites in a region, risk would be expected to vary across sites due to differences in site characteristics that affect transport and fate. A methodology is developed to evaluate such variability. It is applied to Ross County, Ohio, a region for which compiled, detailed hydrogeologic information is available. Four carcinogenic contaminants (benzene, trichloroethylene, chlordane, and benzo[a]pyrene) and exposure scenarios (on-site commercial, on-site recreational, and on-site and off-site residential) are evaluated. Results vary, but in general, indicate that for contaminants that are highly degradable such as benzene or immobile in the subsurface such as benzo[a]pyrene, specifying a uniform soil remediation goal would result in relatively small degree of regional risk variability. However, for highly mobile and persistent contaminants like trichloroethylene, a uniform goal would result in a large degree of regional risk variability. Application of the methodology to a larger, less well-characterized region is analyzed.
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References
1.
Aller, L., Bennett, T., Lehr, J. H., and Petty, R. (1985). “DRASTIC: a standardized system for evaluating groundwater pollution potential using hydrogeologic settings.”EPA/600/2-85/018, R. S. Kerr Envir. Res. Lab, U.S. EPA, Ada, Okla.
2.
Brakensiek, D. L., Engleman, R. L., and Rawls, W. J.(1981). “Variations within texture classes of soil water parameters.”Trans. of ASAE, 24, 335–339.
3.
Boutwell, S. H., Brown, S. M., Roberts, B. R., and Atwood, D. F. (1985). “Modeling remedial actions at uncontrolled hazardous waste sites.”EPA/540/2-85/001, Off. of Res. and Devel., U.S. EPA, Washington, D.C.
4.
Chiang, C. Y., Salanitro, J. P. Chai, E. Y., Colthart, and J. D., and Klein(1988). “Aerobic biodegradation of benzene, toluene, and xylene in a sandy aquifer—data analysis and computer modeling.”Ground Water, 27(6), 823–834.
5.
Chiou, C. T., Peters, L. J., and Freed, V. H.(1979). “A physical concept of soil water equilibria for non-ionic organic compounds.”Sci., 206, 831–832.
6.
Cowherd, C. J., Muleski, G. E., Englehart, P. J., and Gillette, D. A. (1985). “Rapid assessment of exposure to particulate emissions from surface contamination sites.”PB85-192219, Ofc. of Res. and Devel., U.S. EPA, Washington, D.C.
7.
Davidson, I. W., and Beliles, R. P. (1991). “Consideration of the target organ toxicity of tricholoroethylene in terms of metabolite toxicity and pharmacokinetics.”Drug Metabolism Rev., 23(5,6), 493–599.
8.
Dean, J. A., Editor. (1985). Lange's handbook of chemistry, 11th Ed. McGraw Hill, Inc., New York, N.Y.
9.
Donigian, A. S., Yo, T. Y., and Shanahan, E. W. (1983). “Rapid assessment of potential groundwater contamination under emergency response conditions.”EPA-600/8-83-030, U.S. EPA, Washington, D.C.
10.
Feldman, M. D., and Mailbach, H. I.(1970). “Absorption of some organic compounds in skin in man.”J. Investigative Dermatology, 54(5), 399–404.
11.
Frederick, C. L. (1991). “Ground water pollution potential of Ross County, Ohio.”Rep. No. 24, Ohio Dept. of Nat. Resour., Columbus, Ohio.
12.
Freeze, R., and Cherry, J. A. (1979). Groundwater . Prentice-Hall, Inc., Englewood Cliffs, N.J.
13.
Gelhar, L. W., Mantoglou, A., Welty, C., and Rehfeldt, K. R. (1985). “A review of field-scale solute transport processes in saturated and unsaturated porous media.”EA-4190 RP-2485-05, Electric Power Res. Inst., Palo Alto, Calif.
14.
Grisham, J. W. (1986). Health aspects of the disposal of waste chemicals . Pergamon Press, New York, N.Y.
15.
Iman, R. L. (1984). “A FORTRAN 77 program and user's guide for the generation of latin hypercube and random samples for use with computer models.”SAND83-2365, Sandia Nat. Lab., Albuquerque, N.M.
16.
Jeffers, P. M., Ward, L. M., Woytowitch, L. M., and Wolfe, N. L.(1989). “Homogeneous hydrolysis rate constants for selected chlorinated methanes, ethanes, ethenes, and propanes.”Envir. Sci. Technol., 23(8), 965–9.
17.
Jury, W. A., Russo, D., Streile, G., and Hesham, E. A.(1990). “Evaluation of volatilization by organic chemicals residing below the soil surface.”Wat. Resour. Res., 26(1), 13–20.
18.
Karickhoff, S. W., Brown, D. S., and Scott, T. A.(1979). “Sorption of hydrophobic pollutants and natural sediments.”Water Res., 13, 241–48.
19.
Labieniec, P. A. (1994). “The risk implications of approaches for setting soil remediation goals at hazardous waste contaminated sites,” PhD thesis, Carnegie Mellon Univ., Pittsburgh, Pa.
20.
Labieniec, P. A., Dzombak, D. A., and Siegrist, R. L. (1994). “Risk variability from uniform soil remediation goals for PCBs.”J. Envir. Engrg., ASCE 120(3), 495–512.
21.
Labieniec, P. A., Dzombak, D. A., and Siegrist, R. L.(1996). “SoilRisk: a risk assessment model for organic contaminants in soil.”J. Envir. Eng., ASCE, 122(5), 388–398.
22.
Lyman, W. J., Reehl, W. F., and Rosenblatt, D. H. (1990). Handbook of chemical property estimation methods . Am. Chem. Soc., Washington, D.C.
23.
Montgomery, J. H., and Welkom, L. M. (1990). Groundwater chemicals desk reference . Lewis Publishers, Inc., Chelsea, Mich.
24.
Morgan, M. G., and Henrion, M. (1990). Uncertainty: a guide to dealing with uncertainty in quantitative risk and policy analysis . Cambridge Univ. Press, Cambridge, England.
25.
Munz, C., and Roberts, P. V.(1987). “Air-water phase equilibria of volatile organic solutes.”J. Am. Water Works Assoc., 79(5), 62–69.
26.
Puri, R. K., et al. (1990). “Studies on the transport and fate of chlordane in the environment.”Long range transport of pesticides, D. A. Kurtz, ed., Lewis Publishers, Inc., Chelsea, Mich., 270–89.
27.
Rak, A. (1994). “An ecological risk assessment for nationally uniform soil criteria,” Masters thesis, Duke Univ., School of the Envir., Durham, N.C.
28.
Roberts, P. V., and Dandliker, P. G.(1983). “Mass transfer of volatile organics from aqueous solution to the atmosphere during surface aeration.”Envir. Sci. Technol., 17(8), 484–489.
29.
Schaum, J., Hoang, K., Kinerson, R., Moya, J., and Wang, R. (1992). “Estimating dermal and inhalation exposure to volatile chemicals in domestic water.”Drinking water contamination and health: integration of exposure assessment, toxicology, and risk assessment, R. Wang, ed., Marcel Dekker, New York, N.Y.
30.
Seinfeld, J. H. (1986). Atmospheric chemistry and physics of air pollution . John Wiley and Sons, Inc., New York, N.Y.
31.
Sims, R. C., Doucette, W. J., McLean, J. E., Grenney, W. J., and Ryan Dupont, R. (1988). “Treatment potential for 56 EPA listed hazardous chemicals in soil.”EPA/600/6-88/001, R. S. Kerr Envir. Res. Lab, U.S. EPA, Ada, Okla.
32.
Smith, V. J., and Charbeneau, R. J.(1990). “Probabilistic soil contamination exposure assessment procedures.”J. Envir. Engrg., ASCE, 116(6), 1143–1163.
33.
Stephenson, R. M., and Malanowski, S. (1987). Handbook of thermodynamics of organic compounds . Elsevier Applied Science Publishers, Ltd., New York, N.Y.
34.
U.S. Environmental Protection Agency. (1989). “Risk assessment guidance for Superfund volume I: human health evaluation manual (Part A).”EPA/540/1-89/002, Ofc. of Emergency and Remedial Response, Washington, D.C.
35.
U.S. Environmental Protection Agency. (1990). Integrated risk information system (IRIS) . Ofc. of Res. and Devel., Washington, D.C.
36.
U.S. Environmental Protection Agency. (1991a). “Description and sampling of contaminated soils.”EPA/625/12-91/002, Ctr. for Envir. Res. Information, Cincinnati, Ohio.
37.
U.S. Environmental Protection Agency. (1991b). “Risk assessment guidance for Superfund volume I: human health evaluation manual supplemental guidance `standard default exposure factors' interim final.”PB91-921314, Ofc. of Emergency and Remedial Response, Washington, D.C.
38.
U.S. Environmental Protection Agency. (1993). “Health effects assessment summary tables annual update.”EPA 540-R-93-058, Ofc. of Solid Waste and Emergency Response, Washington, D.C.
39.
U.S. Environmental Protection Agency. (1994). “Soil screening level guidance draft.”PB95-963529, Ofc. of Solid Waste and Emergency Response, Washington, D.C.
40.
Verschuren, K. (1983). Handbook of environmental data on organic chemicals, 2nd ed., Van Nostrand Reinhold Co., New York, N.Y.
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Copyright © 1996 American Society of Civil Engineers.
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Published online: Jul 1, 1996
Published in print: Jul 1996
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