Pyrolysis Kinetics of Uncoated Printing and Writing Paper of MSW
Publication: Journal of Environmental Engineering
Volume 122, Issue 4
Abstract
The pyrolysis kinetics of cellulosic uncoated printing and writing paper, which is one of the principal materials contributing to the municipal solid waste (MSW) of Taiwan, was investigated with a thermal gravimetric analysis (TGA) reaction system. The experiments were carried out in a nitrogen environment in the 450–850 K temperature range at various constant heating rates of 1, 2, and 5 K/min. The results indicated that there were two principal reactions in TGA curves as distinguished by the two significant and distinct mass changes over the experimental conditions. The pyrolysis of uncoated printing and writing paper can be adequately described by a two-reaction model. The corresponding activation energies, preexponential factors, and reaction orders were determined. The experimental results were satisfactorily fitted by the proposed chemical reaction model.
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References
1.
Agrawal, R. K. (1988a). “Kinetic of reactions involved in pyrolysis of cellulose. I: The three reaction model.”Can. J. Chemical Engrg., Vol. 66, 403–412.
2.
Agrawal, R. K. (1988b). “Kinetics of reactions involved in pyrolysis of cellulose. II: The modified Kilzer-Broido model.”Can. J. Chemical Engrg., Vol. 66, 413–418.
3.
Agrawal, R. K., and McCluskey, R. J. (1983). “The low pressure pyrolysis of newsprint.”J. Appl. Polymer Sci., Vol. 27, 367–382.
4.
Antal, M. J., Friedman, H. L. Jr., and Rogers, F. E. (1980). “Kinetics of cellulose pyrolysis in nitrogen and stream.”Combustion Sci. & Technol., Vol. 21, 141–152.
5.
Arouz, A. Z., and Önsan, A. I. (1987). “Pyrolysis of solid waste materials.”Chimica Acta Turcica, Turkey, Vol. 15, 415–429.
6.
Bradbury, A. G. W., Sakai, Y., and Shafizadeh, F. (1979). “A kinetic model for pyrolysis of cellulose.”J. Appl. Polymer Sci., Vol. 23, 3271–3280.
7.
Buekens, A. G., and Schoeters, J. G.(1986). “European experience in the pyrolysis and gasification of solid wastes.”Conservation & Recycling, England, 9(3), 253–269.
8.
Calahorra, M. E., Cortázar, M., Eguiazábal, J. I., and Guzmán, G. M. (1989). “Thermogravimetric analysis of cellulose: effect of the molecular weight on thermal decomposition.”J. Appl. Polymer Sci., Vol. 37, 3305–3314.
9.
Diebold, J., Evans, R., and Scabill, J. (1990). “Fast pyrolysis of RDF to produce fuel oils, char, and a metal-rich by-product.”Energy Biomass Wastes, Vol. 13, 851–878.
10.
Fairbridge, C., Ross, R. A., and Sood, S. P. (1978). “A kinetic and surface study of the thermal decomposition of cellulose powder in inert and oxidizing atmospheres.”J. Appl. Polymer Sci., Vol. 22, 497–510.
11.
Gullett, B. K., and Smith, P. (1987). “Thermogravimetric study of the decomposition of pelletized cellulose at 315°C–800°C.”Combustion & Flame, Vol. 67, 143–151.
12.
Hoffman, D. A., and Fitz, R. A.(1968). “Batch retort pyrolysis of solid municipal wastes.”Envir. Sci. and Technol., 2(11), 1023–1026.
13.
Kilzer, F. J., and Broido, A. (1965). “Speculations on the nature of cellulose pyrolysis.”Pyrodynamics, Vol. 2, 151–159.
14.
Levie, B., Diebold, J. P., and West, R. (1988). “Pyrolysis of single pellets of refuse derived fuel.”Res. Thermochemistry Biomass Conversion, A. V. Bridgewater and J. L. Kuester, eds., Elsevier, London, England, 312–326.
15.
Mallya, N., and Helt, J. E. (1988). “Potential for converting MSW to useful fuels through pyrolysis.”Proc., 13th Nat. Waste Process Conf., Am. Chemical Soc., Washington, D.C., 295–300.
16.
Nguyen, T., Zavarin, E., and Barrall, E. M. II. (1981). “Thermal analysis of lignocellulosic materials. I: Unmodified materials.”J. Macromolecular Sci.-Rev. Macromolecular Chem., C20(1), 1–65.
17.
Nishizaki, H. (1980). “Comparative study of various methods for thermogravimetric analysis of polystyrene degradation.”J. Appl. Polymer Sci., Vol. 25, 2869–2877.
18.
Ozawa, T.(1965). “A new method of analyzing thermogravimetric data.”Bull. Chemical Soc. Japan, 38(11), 1881–1886.
19.
Petrović, Z. S., and Zavargo, Z. Z. (1986). “Reliability of methods for determination of kinetic parameters from thermogravimetry and DSC measurements.”J. Appl. Polymer Sci., Vol. 32, 4353–4367.
20.
Reed, T. B. (1981). Biomass gasification principles and technology . Noyes Data Corp., Park Ridge, N.J.
21.
Roberts, A. F. (1970). “The kinetic behavior of intermediate compounds during the pyrolysis of cellulose.”J. Appl. Polymer Sci., Vol. 14, 244–246.
22.
Rogers, F. E., and Ohlemiller, T. J. (1980). “Cellulosic insulation material. I: Overall degradation kinetics and reaction heats.”Combustion Sci. & Technol., Vol. 24, 129–137.
23.
Shafizadeh, F., and Bradbury, A. G. W. (1979). “Thermal degradation of cellulose in air and nitrogen at low temperatures.”J. Appl. Polymer Sci., Vol. 23, 1431–1442.
24.
Šimkovic, I., Ďurindová, M., Mihálov, V., and Königstein, J. (1986). “Thermal degradation of cellulose model compounds in inert atmosphere.”J. Appl. Polymer Sci., Vol. 31, 2433–2441.
25.
Wu, C. H., Chang, C. Y., Hor, J. L., Shih, S. M., Chen, L.W., and Chang, F. W. (1993). “On the thermal treatment of plastic mixtures of MSW: pyrolysis kinetics.”Waste Mgmt., Vol. 13, 221–235.
26.
Yang, W. F. (1991). “An engineering project for garbage incineration plant of Taipei City: sampling and analyses of garbage at eighth year.”Rep., Envir. Protection Bureau of Taipei, Taiwan, Republic of China, 24.
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Copyright © 1996 American Society of Civil Engineers.
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Published online: Apr 1, 1996
Published in print: Apr 1996
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