Feasibility of Fullerene Waste as Carbonaceous Adsorbent
Publication: Journal of Environmental Engineering
Volume 122, Issue 3
Abstract
This note investigates using the waste soot generated in fullerene manufacture as an adsorbent. Both oven-dried and air-activated samples of waste soot are compared with three commercially available powdered activated carbons (PACs): Nuchar-SA, HDH, and Calgon-RC. Three model compounds were chosen for adsorbtion tests—TCE, Benzene, and Phenol—representing a small branched molecule, a small nonpolar ring molecule, and relatively polar ring molecule. Additionally, the effectiveness of total organic carbon (TOC) removal from wastewater was evaluated. Oven-dried soot performed poorly as compared to the commercial carbons, but activation of the waste soot for 60 min at 450°C in air resulted in an activated carbon (aFWS) with properties similar to those of commercially available PACs. The aFWS performed better than one would predict from the typical characterization measures of iodine number, molasses number, and methylene blue number. The data for phenol suggests some functional groups are created during the activation of the waste soot. These results show that large-scale fullerene manufacturing can be a zero-waste industry, because its primary waste product can be converted into a useful material.
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References
1.
Boucher, F. B., Knell, E. W., Preston, G. T., and Mallan, G. M. (1977). “Pyrolysis of industrial wastes for oil and activated carbon recovery.”Rep. EPA-600/2-77-091, U.S. Envir. Protection Agency, Cincinnati, Ohio.
2.
Chang, Y. J., Chan, D. H., and Yaws, C. L. (1992). “Data compilation for soil sorption coefficient.”Pollution Engrg., (June 15), 54–60.
3.
Dandy, A. J.(1977). “Production and characterization of activated carbons from agricultural waste products and wood charcoal.”New Zealand J. Sci., 20, 291–294.
4.
Ford, D. L. (1981). “Wastewater characteristics and treatment.”Activated carbon adsorption for wastewater treatment, J. R. Perrich, CRC Press Inc., Boca Raton, Fla., 1–28.
5.
Ismail, I. M. K., and Rodgers, S. I.(1992). “Comparisons between fullerene and forms of well-known carbons.”Carbon, 30(2), 229–239.
6.
Kline, S. J., and McClintock, F. A. (1953). “Describing uncertainties in single-sample experiments.”Mech. Engrg., (Jan.), 3.
7.
Kochetkova, R. P., Voronkov, V. V., Sorkin, E. I., Polyakov, V. V., Korobeinikova, M. G., and Apasov, V. L.(1989). “Production of carbonaceous sorbent from wastes obtained in the vortex combustion of fuel in the boiler units of thermoelectric power stations.”Solid Fuel Chem., 23(2), 125–129.
8.
Marsh, H., Iley, M., Berger, J., and Siemieniewska, T.(1975). “The adsorptive properties of activated plum stone chars.”Carbon, 13, 103–109.
9.
Mattson, J. S., Mark, H. B. Jr., Malbin, M. D., Weber, W. J. Jr., and Crittenden, J. C.(1969). “Surface chemistry of active carbon: specific adsorption of phenols.”J. Colloid Interface Sci., 31, 116.
10.
Mirasol, J. Rodriguez, Cordero, T., and Rodriguez, J. J.(1993). “Preparation and characterization of activated carbons from Eucalyptus Kraft Lignin.”Carbon, 31(1), 87–95.
11.
Pang, L. S. K., Vasallo, A. M., and Wilson, M. A.(1992). “Fullerenes from coal: A self consistent preparation and purification process.”Energy and Fuels, 6(2), 176–179.
12.
Pokonova, Yu. V.(1992). “Utilization of petroleum residues for production of carbon adsorbents.”Fuel Sci. and Technol. Int., 10(1), 95–107.
13.
Polak, J., and Lu, B. C. Y.(1973). “Mutual solubilities of hydrocarbons and water at 0 and 25°C.”Can. J. Chem., 51, 4018–4023.
14.
Roberts, P. V., Mackay, D. M., and Cannon, F. S. (1980). “Preparation and evaluation of powdered activated carbon from lignocellulosic materials.”Rep., EPA-600/2-80-123, U.S. Envir. Protection Agency, Cincinnati, Ohio.
15.
Scheiter, M., Dragun, J., and Kalinowski, T. W.(1985). “A carbon adsorption isotherm test for volatile organic chemicals in water.”J. Water Pollution Control Federation, 57(5), 403–405.
16.
Sittig, M. (1981). Handbook of toxic and hazardous chemicals, Noyes Publ., Park Ridge, N.J.
17.
Srivastava, S. K., Tyagi, R., and Pant, N.(1989). “Adsorption of heavy metal ions on carbonaceous material developed from the waste slurry generated in local fertilizer plants.”Water Res., 23(9), 1161–1165.
18.
U.S. Environmental Protection Agency (EPA). (1973). Process design manual for carbon adsorption . Cincinnati, Ohio.
19.
Wolfe, J. R. (1979). “The use of PAC and PAC-GAC filters for TOC removal in drinking water treatment,” MS thesis, Dept. of Civ. and Envir. Engrg., Univ. of Houston, Houston, Tex.
20.
Zanitsch, R. H., and Stenzel, M. H. (1978). “Economics of granular activated carbon water and wastewater treatment systems.”Carbon adsorption handbook, Cheremisinoff and Ellerbusch, eds., Ann Arbor Science Publishers, Inc., Ann Arbor, Michigan, 215–240.
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Copyright © 1996 American Society of Civil Engineers.
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Published online: Mar 1, 1996
Published in print: Mar 1996
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