TECHNICAL PAPERS
May 1, 1993

Modeling Cadmium Fate at Superfund Site: Impact of Bioturbation

Publication: Journal of Environmental Engineering
Volume 119, Issue 3

Abstract

A model of cadmium fate in the Foundry Cove Superfund site is calibrated to the postloading period from 1972 to 1989. Bioturbation (i.e. benthic mixing) of sediment cadmium is calculated to be primarily responsible for the slow decline in surface cadmium over this period. Such mixing increases the flux of cadmium from the cove by about an order of magnitude over the case of no mixing. Hindcasting previous cadmium exposure from consumption of contaminated blue crabs indicates an increased exposure of about 25 times acceptable levels during the peak loading period of 1965–70. Simulation of remedial controls indicates that if no action is taken, cadmium concentrations will continue to be at elevated levels at least to the year 2012. Capping of the inner cove with clean sand over an impermeable barrier (equivalent to “removal” of sediment cadmium), however, results in an immediate and constant decrease in cadmium to background levels.

Get full access to this article

View all available purchase options and get full access to this article.

References

1.
Aller, R. C. (1982). “The effects of macrobenthos on chemical properties of marine sediment and overlying water.” Animal‐sediment relations, P. L. McCall and Tevesz, M. J. S., eds., Plenum Press, New York, N.Y., 53–102.
2.
Bergoffen, A. (1991). “Modeling the concentration of cadmium in blue crabs of Foundry Cove,” MSc thesis, Manhattan College, N.Y.
3.
Bopp, R. F. (1979). “The geochemistry of polychlorinated biphenyls in the Hudson River,” PhD dissertation, Columbia University, New York, N.Y.
4.
Bower, P. M., Simpson, H. J., Williams, S. C., and Li, Y. H. (1978). “Heavy metals in the sediments of Foundry Cove, Cold Spring, New York.” Envir. Sci. & Tech., 12(6), 683–687.
5.
Development of a steady state water quality model for New York Harbor. Volume I. (1975). Interstate Sanitation Commission, New York, N.Y.
6.
Di Toro, D. M., Mahony, J. D., Hansen, D. J., Scott, K. J., Hicks, M. B., Mayr, S. M., and Redmond, M. S. (1990). “Toxicity of cadmium in sediments: the role of acid volatile sulfide.” Envir. Toxicology & Chem., 9, 1487–1502.
7.
Hazen, R. E., and Kneip, T. J. (1980). “Biogeochemical cycling of cadmium in a marsh ecosystem.” Cadmium in the environment. Part I: Ecological Cycling, J. O. Nriagu, ed., John Wiley & Sons, N.Y., 399–424.
8.
Klerks, P. L., and Levinton, J. S. (1989). “Effects of heavy metals in a polluted aquatic ecosystem.” Ecotoxicology: problems and approaches, S. A. Levin, M. A. Harwell, J. R. Kelly and K. D. Kimball, eds., Springer‐Verlag, N.Y., 41–67.
9.
Kneip, T. J., and Hazen, R. E. (1979). “Deposit and mobility of cadmium in a marsh‐cove ecosystem and the relation to cadmium concentration in biota.” Envir. Health Perspect., 28(Feb.), 67–73.
10.
Knutson, A. B., Klerks, P. L., and Levinton, J. S. (1987). “The fate of metal contaminated sediments in Foundry Cove, New York.” Envir. Poll., 45, 291–304.S
11.
“Marathon Battery site, Cold Spring, New York remedial investigation/feasibility study.” (1985). Tech. Memo. No. 7: summary of environmental investigations, sediment and water quality, Acres Int. Corp., Buffalo, N.Y.
12.
Matisoff, G. (1982). “Mathematical models of bioturbation.” Animal‐sediment relations, P. L. McCall and M. J. S. Tevesz, eds., Plenum Press, New York, N.Y., 289–330.
13.
Olsen, C. R. (1979). “Radionuclides, sedimentation and the accumulation of pollutants in the Hudson estuary,” PhD dissertation, Columbia University, New York, N.Y.
14.
“Preliminary site background data analysis of Foundry Cove, Cold Spring, Putnam County, New York.” (1983). Rep., Vinson & Elkins, Houston, Tex.
15.
Superfund public health evaluation manual; EPA 540/1‐86/060. (1986). Ofc. Emergency and Remediation Res., U.S. Environmental Protection Agency, Washington, D.C.
16.
Technical guidance manual for performing waste load allocations. Book II: streams and rivers; chapter 3, toxic substances; EPA‐440/4‐84‐022. (1984). U.S. Environmental Protection Agency, Washington, D.C.
17.
Thomann, R. V., Mueller, J. A., Winfield, R. P., and Huang, C‐R. (1991). “Model of fare and accumulation of PCB homologues in Hudson Estuary.” J. Envir. Engrg., ASCE, 117(2), 161–178.
18.
Wiedow, M. A. (1981). “Distribution and binding of cadmium in the blue crab (Callinectes sapidus): implication in human health,” PhD dissertation, New York University, New York, N.Y.

Information & Authors

Information

Published In

Go to Journal of Environmental Engineering
Journal of Environmental Engineering
Volume 119Issue 3May 1993
Pages: 424 - 442

History

Received: Dec 9, 1991
Published online: May 1, 1993
Published in print: May 1993

Permissions

Request permissions for this article.

Authors

Affiliations

Robert V. Thomann, Member, ASCE
Prof., Envir. Engrg. and Sci. Program, Manhattan Coll., Riverdale, NY 10471
William Merklin
John Carollo Engrs., 3655 Noble Dr., Ste. 120, San Diego, CA 92122
Beate Wright
1 LT, A Co., 187th Med. Bn., AHS Box 36, Fort Sam Houston, TX 78234‐6100

Metrics & Citations

Metrics

Citations

Download citation

If you have the appropriate software installed, you can download article citation data to the citation manager of your choice. Simply select your manager software from the list below and click Download.

Cited by

View Options

Get Access

Access content

Please select your options to get access

Log in/Register Log in via your institution (Shibboleth)
ASCE Members: Please log in to see member pricing

Purchase

Save for later Information on ASCE Library Cards
ASCE Library Cards let you download journal articles, proceedings papers, and available book chapters across the entire ASCE Library platform. ASCE Library Cards remain active for 24 months or until all downloads are used. Note: This content will be debited as one download at time of checkout.

Terms of Use: ASCE Library Cards are for individual, personal use only. Reselling, republishing, or forwarding the materials to libraries or reading rooms is prohibited.
ASCE Library Card (5 downloads)
$105.00
Add to cart
ASCE Library Card (20 downloads)
$280.00
Add to cart
Buy Single Article
$35.00
Add to cart

Get Access

Access content

Please select your options to get access

Log in/Register Log in via your institution (Shibboleth)
ASCE Members: Please log in to see member pricing

Purchase

Save for later Information on ASCE Library Cards
ASCE Library Cards let you download journal articles, proceedings papers, and available book chapters across the entire ASCE Library platform. ASCE Library Cards remain active for 24 months or until all downloads are used. Note: This content will be debited as one download at time of checkout.

Terms of Use: ASCE Library Cards are for individual, personal use only. Reselling, republishing, or forwarding the materials to libraries or reading rooms is prohibited.
ASCE Library Card (5 downloads)
$105.00
Add to cart
ASCE Library Card (20 downloads)
$280.00
Add to cart
Buy Single Article
$35.00
Add to cart

Media

Figures

Other

Tables

Share

Share

Copy the content Link

Share with email

Email a colleague

Share