Technical Papers
Oct 28, 2019

Downstream Processing of Palm Oil Mill Effluent in a CBME Reactor

Publication: Journal of Hazardous, Toxic, and Radioactive Waste
Volume 24, Issue 1

Abstract

This study describes a laboratory-scale continuous-flow bipolar mode electrocoagulation (CBME) unit that was developed as a downstream process unit for polishing an anaerobically treated palm oil mill effluent (POME). The design of the CBME reactor has the advantage of achieving good treatment efficiency with lesser energy consumption when compared to monopolar electrocoagulation systems. The process optimization was carried out for maximum removal of total organic carbon (TOC) and total phosphorus (TP) using response surface methodology (RSM). The independent process variables selected are initial pH, retention time (RT), reaction area (RA), and current density (CD). The optimum condition was achieved when pH was set at 6.4, retention time at 7.7 min, reaction (electrode) area at 765 cm2, and current density at 77.8  A/m2. Under this condition, 77% and 73% of TOC and TP removals were observed, respectively. The ratio of the total surface area of electrodes to the volume of the reactor was found to be 76.5  m1 at the optimum operating condition. The energy consumption at the optimum point was 22.4  kW·h/m3 of wastewater treated. Micropollutants were screened for the organic constituents present before and after the treatment using high-resolution mass spectroscopy (HRMS).

Get full access to this article

View all available purchase options and get full access to this article.

Data Availability Statement

All data, models, and code generated or used during the study appear in the submitted article.

Acknowledgments

This study was partly funded by the Ministry of Human Resource Development, India, through the Frontier Areas of Science and Technology (FAST) program, and partly by Rahyals Envergy India Pvt Ltd. We thank Mr. Prashant Joseph, Application Engineer-LCMS from Agilent Technologies India Pvt Ltd. for extending his support in LC-HRMS analysis.

References

Ahmad, A. L., M. F. Chong, S. Bhatia, and S. Ismail. 2006. “Drinking water reclamation from palm oil mill effluent (POME) using membrane technology.” Desalination 191 (1–3): 35–44. https://doi.org/10.1016/j.desal.2005.06.033.
APHA/AWWA/WEF (American Public Health Association/American Water Works Association/Water Environment Federation). 2012. Standard methods for examination of water and wastewater. 22nd ed. Washington, DC: APHA/AWWA/WEF.
Assémian, A. S., K. E. Kouassi, P. Drogui, K. Adouby, and D. Boa. 2018. “Removal of a persistent dye in aqueous solutions by electrocoagulation process: Modeling and optimization through response surface methodology.” Water Air Soil Pollut. 229 (6): 184. https://doi.org/10.1007/s11270-018-3813-2.
Bashir, M. J. K., T. Mau Han, L. Jun Wei, N. Choon Aun, and S. S. Abu Amr. 2016. “Polishing of treated palm oil mill effluent (POME) from ponding system by electrocoagulation process.” Water Sci. Technol. 73 (11): 2704–2712. https://doi.org/10.2166/wst.2016.123.
Bezerra, M. A., R. E. Santelli, E. P. Oliveira, L. S. Villar, and L. A. Escaleira. 2008. “Response surface methodology (RSM) as a tool for optimization in analytical chemistry.” Talanta 76 (5): 965–977. https://doi.org/10.1016/j.talanta.2008.05.019.
Chavalparit, O., and M. Ongwandee. 2009. “Optimizing electrocoagulation process for the treatment of biodiesel wastewater using response surface methodology.” J. Environ. Sci. 21 (11): 1491–1496. https://doi.org/10.1016/S1001-0742(08)62445-6.
Damaraju, M., D. Bhattacharyya, and K. K. Kurilla. 2017. “Removal of recalcitrant carbon from an industrial wastewater using electrocoagulation.” Int. J. Civ. Eng. 15 (4): 697–703. https://doi.org/10.1007/s40999-017-0187-6.
Dastyar, W., T. Amani, and S. Elyasi. 2015. “Investigation of affecting parameters on treating high-strength compost leachate in a hybrid EGSB and fixed-bed reactor followed by electrocoagulation-flotation process.” Process Saf. Environ. Prot. 95 (May): 1–11. https://doi.org/10.1016/j.psep.2015.01.012.
Drogui, P., M. Asselin, S. K. Brar, H. Benmoussa, and J. F. Blais. 2008. “Electrochemical removal of pollutants from agro-industry wastewaters.” Sep. Purif. Technol. 61 (3): 301–310. https://doi.org/10.1016/j.seppur.2007.10.013.
Elabbas, S., N. Ouazzani, L. Mandi, F. Berrekhis, M. Perdicakis, S. Pontvianne, M. N. Pons, F. Lapicque, and J. P. Leclerc. 2016. “Treatment of highly concentrated tannery wastewater using electrocoagulation: Influence of the quality of aluminium used for the electrode.” J. Hazard. Mater. 319 (Dec): 69–77. https://doi.org/10.1016/j.jhazmat.2015.12.067.
Emamjomeh, M. M., H. A. Jamali, and M. Moradnia. 2017. “Optimization of nitrate removal efficiency and energy consumption using a batch monopolar electrocoagulation: Prediction by RSM method.” J. Environ. Eng. 143 (7): 04017022. https://doi.org/10.1061/(ASCE)EE.1943-7870.0001210.
Fernandes, A., T. Jesus, R. Silva, M. J. Pacheco, L. Ciríaco, and A. Lopes. 2017. “Effluents from anaerobic digestion of organic wastes: Treatment by chemical and electrochemical processes.” Water Air Soil Pollut. 228 (11): 1–8. https://doi.org/10.1007/s11270-017-3620-1.
Gengec, E., M. Kobya, E. Demirbas, A. Akyol, K. Oktor, and A. Al. 2012. “Optimization of baker’s yeast wastewater using response surface methodology by electrocoagulation.” Desalination 286 (Feb): 200–209. https://doi.org/10.1016/j.desal.2011.11.023.
Golder, A. K., A. N. Samanta, and S. Ray. 2007. “Removal of Cr3+by electrocoagulation with multiple electrodes: Bipolar and monopolar configurations.” J. Hazard. Mater. 141 (3): 653–661. https://doi.org/10.1016/j.jhazmat.2006.07.025.
Hassan, I., I. Nirdosh, and G. H. Sedahmed. 2015. “Separation of oil from oil-water emulsions by electrocoagulation in an electrochemical reactor with a fixed-bed anode.” Water Air Soil Pollut. 226 (8): 271. https://doi.org/10.1007/s11270-015-2521-4.
Ilhan, F., U. Kurt, O. Apaydin, and M. T. Gonullu. 2008. “Treatment of leachate by electrocoagulation using aluminum and iron electrodes.” J. Hazard. Mater. 154 (1–3): 381–389. https://doi.org/10.1016/j.jhazmat.2007.10.035.
Isarain-Chávez, E., C. La Rosa, L. A. Godínez, E. Brillas, and J. M. Peralta-Hernández. 2014. “Comparative study of electrochemical water treatment processes for a tannery wastewater effluent.” J. Electroanal. Chem. 713 (Jan): 62–69. https://doi.org/10.1016/j.jelechem.2013.11.016.
Kausley, S. B., C. P. Malhotra, and A. B. Pandit. 2017. “Treatment and reuse of shale gas wastewater: Electrocoagulation system for enhanced removal of organic contamination and scale causing divalent cations.” J. Water Process Eng. 16 (Apr): 149–162. https://doi.org/10.1016/j.jwpe.2016.11.003.
Liew, W. L., M. A. Kassim, K. Muda, S. K. Loh, and A. C. Affam. 2014. “Conventional methods and emerging wastewater polishing technologies for palm oil mill effluent treatment: A review.” J. Environ. Manage. 149 (Feb): 222–235. https://doi.org/10.1016/j.jenvman.2014.10.016.
Makwana, A. R., and M. M. Ahammed. 2017. “Electrocoagulation process for the post-treatment of anaerobically treated urban wastewater.” Sep. Sci. Technol. 52 (8): 1412–1422. https://doi.org/10.1080/01496395.2017.1288139.
Mollah, M. Y. A., P. Morkovsky, J. A. G. Gomes, M. Kesmez, J. Parga, and D. L. Cocke. 2004. “Fundamentals, present, and future perspectives of electrocoagulation.” J. Hazard. Mater. 114 (1–3): 199–210. https://doi.org/10.1016/j.jhazmat.2004.08.009.
Nariyan, E., C. Wolkersdorfer, and M. Sillanpää. 2018. “Sulfate removal from acid mine water from the deepest active European mine by precipitation and various electrocoagulation configurations.” J. Environ. Manage. 227 (Dec): 162–171. https://doi.org/10.1016/j.jenvman.2018.08.095.
Nasution, A., B. L. Ng, E. Ali, Z. Yaakob, B. L. N. Ansori Nasution, E. Ali, Z. Yaakob, and S. K. Kamarudin. 2014. “Electrocoagulation of palm oil mill effluent for treatment and hydrogen production using response surface methodology.” Pol. J. Environ. Stud. 23 (5): 1669–1677.
Ozay, Y., E. K. Ünşar, Z. Işık, F. Yılmaz, N. Dizge, N. A. Perendeci, M. A. Mazmanci, and M. Yalvac. 2018. “Optimization of electrocoagulation process and combination of anaerobic digestion for the treatment of pistachio processing wastewater.” J. Clean. Prod. 196 (Sep): 42–50. https://doi.org/10.1016/j.jclepro.2018.05.242.
Phalakornkule, C., J. Mangmeemak, K. Intrachod, and B. Nuntakumjorn. 2010. “Pretreatment of palm oil mill effluent by electrocoagulation and coagulation.” ScienceAsia 36 (2): 142–149. https://doi.org/10.2306/scienceasia1513-1874.2010.36.142.
Qin, X., B. Yang, F. Gao, and G. Chen. 2013. “Treatment of restaurant wastewater by pilot-scale electrocoagulation-electroflotation: Optimization of operating conditions.” J. Environ. Eng. 139 (7): 1004–1016. https://doi.org/10.1061/(ASCE)EE.1943-7870.0000687.
Rout, P. R., P. Bhunia, and R. R. Dash. 2017. “Evaluation of kinetic and statistical models for predicting breakthrough curves of phosphate removal using dolochar-packed columns.” J. Water Process Eng. 17 (Feb): 168–180. https://doi.org/10.1016/j.jwpe.2017.04.003.
Rout, P. R., R. R. Dash, and P. Bhunia. 2016. “Nutrient removal from binary aqueous phase by dolochar: Highlighting optimization, single and binary adsorption isotherms and nutrient release.” Process Saf. Environ. Prot. 100 (Mar): 91–107. https://doi.org/10.1016/j.psep.2016.01.001.
Sandhwar, V. K., and B. Prasad. 2017. “Comparative study of electrocoagulation and electrochemical Fenton treatment of aqueous solution of benzoic acid (BA): Optimization of process and sludge analysis.” Korean J. Chem. Eng. 34 (4): 1062–1072. https://doi.org/10.1007/s11814-016-0343-8.
Shojaeimehr, T., F. Rahimpour, M. A. Khadivi, and M. Sadeghi. 2014. “A modeling study by response surface methodology (RSM) and artificial neural network (ANN) on Cu2+ adsorption optimization using light expended clay aggregate (LECA).” J. Ind. Eng. Chem. 20 (3): 870–880. https://doi.org/10.1016/j.jiec.2013.06.017.
Siddhu, N., and J. Saxena. 2017. “Quantification of total phenolic and total flavonoid content of extracts of tagetes erecta flowers.” Asian J. Pharm. Clin. Res. 10 (6): 328. https://doi.org/10.22159/ajpcr.2017.v10i6.14598.
Sincero, A. P., and G. A. Sincero. 2003. Physical chemical treatment of water and wastewater. Washington, DC: CRC Press.
Thakur, L. S., and P. Mondal. 2016. “Techno-economic evaluation of simultaneous arsenic and fluoride removal from synthetic groundwater by electrocoagulation process: Optimization through response surface methodology.” Desalin. Water Treat. 57 (59): 28847–28863. https://doi.org/10.1080/19443994.2016.1186564.
Vasudevan, S., J. Lakshmi, J. Jayaraj, and G. Sozhan. 2009. “Remediation of phosphate-contaminated water by electrocoagulation with aluminium, aluminium alloy, and mild steel anodes.” J. Hazard. Mater. 164 (2–3): 1480–1486. https://doi.org/10.1016/j.jhazmat.2008.09.076.
Wang, C. T., W. L. Chou, and Y. M. Kuo. 2009. “Removal of COD from laundry wastewater by electrocoagulation/electroflotation.” J. Hazard. Mater. 164 (1): 81–86. https://doi.org/10.1016/j.jhazmat.2008.07.122.
Wang, J. P., Y. Z. Chen, Y. Wang, S. J. Yuan, and H. Q. Yu. 2011. “Optimization of the coagulation-flocculation process for pulp mill wastewater treatment using a combination of uniform design and response surface methodology.” Water Res. 45 (17): 5633–5640. https://doi.org/10.1016/j.watres.2011.08.023.

Information & Authors

Information

Published In

Go to Journal of Hazardous, Toxic, and Radioactive Waste
Journal of Hazardous, Toxic, and Radioactive Waste
Volume 24Issue 1January 2020

History

Received: Feb 12, 2019
Accepted: Aug 6, 2019
Published online: Oct 28, 2019
Published in print: Jan 1, 2020
Discussion open until: Mar 28, 2020

Permissions

Request permissions for this article.

Authors

Affiliations

Madhuri Damaraju [email protected]
Research Scholar, Dept. of Civil Engineering, Indian Institute of Technology Hyderabad, Telangana 502285, India. Email: [email protected]
Debraj Bhattacharyya [email protected]
Associate Professor, Dept. of Civil Engineering, Indian Institute of Technology Hyderabad, Telangana 502285, India (corresponding author). Email: [email protected]
Tarun Kanti Panda [email protected]
Professor, Dept. of Chemistry, Indian Institute of Technology Hyderabad, Telangana 502285, India. Email: [email protected]
Kiran Kumar Kurilla [email protected]
Joint Managing Director, Dept. of Environment, Rahyals Envergy India Pvt. Ltd., F-716, Manjeera Majestic Commercial, Kukatpally, Hyderabad, Telangana 500085, India. Email: [email protected]

Metrics & Citations

Metrics

Citations

Download citation

If you have the appropriate software installed, you can download article citation data to the citation manager of your choice. Simply select your manager software from the list below and click Download.

Cited by

View Options

Get Access

Access content

Please select your options to get access

Log in/Register Log in via your institution (Shibboleth)
ASCE Members: Please log in to see member pricing

Purchase

Save for later Information on ASCE Library Cards
ASCE Library Cards let you download journal articles, proceedings papers, and available book chapters across the entire ASCE Library platform. ASCE Library Cards remain active for 24 months or until all downloads are used. Note: This content will be debited as one download at time of checkout.

Terms of Use: ASCE Library Cards are for individual, personal use only. Reselling, republishing, or forwarding the materials to libraries or reading rooms is prohibited.
ASCE Library Card (5 downloads)
$105.00
Add to cart
ASCE Library Card (20 downloads)
$280.00
Add to cart
Buy Single Article
$35.00
Add to cart

Get Access

Access content

Please select your options to get access

Log in/Register Log in via your institution (Shibboleth)
ASCE Members: Please log in to see member pricing

Purchase

Save for later Information on ASCE Library Cards
ASCE Library Cards let you download journal articles, proceedings papers, and available book chapters across the entire ASCE Library platform. ASCE Library Cards remain active for 24 months or until all downloads are used. Note: This content will be debited as one download at time of checkout.

Terms of Use: ASCE Library Cards are for individual, personal use only. Reselling, republishing, or forwarding the materials to libraries or reading rooms is prohibited.
ASCE Library Card (5 downloads)
$105.00
Add to cart
ASCE Library Card (20 downloads)
$280.00
Add to cart
Buy Single Article
$35.00
Add to cart

Media

Figures

Other

Tables

Share

Share

Copy the content Link

Share with email

Email a colleague

Share