Effect of Interfacial Transition Zone on the Carbonation of Cement-Based Materials
Publication: Journal of Materials in Civil Engineering
Volume 29, Issue 7
Abstract
This study dealt with an analysis of the effects of the interfacial transition zone (ITZ) on the carbonation of cement-based material. To this end, a series of experiments dealing with paste and the mortar-gallet interface carbonation were designed and conducted. Experimental results showed that the carbonation depth in the ITZ was several times greater than that in the cement matrix resulting in the emergence of an interfacial effect zone (IEZ). Backscattered electron (BSE) analysis and nanoindentation tests were also conducted on the material to examine the microstructure of the ITZ before and after carbonation and to explore the mechanisms of the ITZ effects. After carbonation, the thickness of the ITZ decreased from 50–60 μm to 20–30 μm, but its porosity was still greater than the porosity of the cement matrix. Therefore, after carbonation, the ITZ was still a weak zone so that the diffusion rate of in the ITZ was higher than in the cement matrix.
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Acknowledgments
The authors acknowledge the financial support from the National Natural Science Foundation of China (No. 51178103). The authors gratefully acknowledge to the Editorbar Language Editing Company for their help in this project.
References
Alexander, M. G., Arliguie, G., Ballivy, G., Bentur, A., and Marchand, J. (1999). “Engineering and transport properties of the interfacial transition zone in cementitious composites.” Univ. of Cape Town, Cape Town, South Africa.
Basheer, L., Basheer, P., and Long, A. (2005). “Influence of coarse aggregate on the permeation, durability and the microstructure characteristics of ordinary Portland cement concrete.” Constr. Build. Mater., 19(9), 682–690.
Bourdette, B., Ringot, E., and Ollivier, J. P. (1995). “Modelling of the transition zone porosity.” Cem. Concr., Res., 25(4), 741–751.
Chang, C. F., and Chen, J. W. (2006). “The experimental investigation of concrete carbonation depth.” Cem. Concr. Res., 36(9), 1760–1767.
Chen, H. S., Sun, W., and Stroeven, P. (2004). “Interfacial transition zone between aggregate and paste in cementitious composites (II).” J. Ceram. Soc., 32(1), 72–79.
Cui, H. Z., and Xing, F. (2010). “Study of interfacial transition zone of light weight aggregate concrete by using SEM and FT- IR.” Concrete, 242(1), 18–20 (in Chinese).
Delagrave, A., et al. (1997). “Influence of the interfacial zone on the chloride diffusivity of mortars.” Adv. Cem. Based. Mater., 5(3–4), 86–92.
Diamond, S. (2001). “Considerations in image analysis as applied to investigations of the ITZ in concrete.” Cem. Concr. Compos., 23(2), 171–178.
Frías, M., and Goni, S. (2013). “Accelerated carbonation effect on behaviour of ternary portland cements.” Composite B, 48(10), 122–128.
Gao, L. X. (2012). “Relationship between porosity and chloride diffusivity in cement-based composite materials.” J. Chongqing Univ., 35(11), 53–61 (in Chinese).
Gao, Y., Schutter, G. D., and Ye, G. (2013). “Micro- and meso-scale pore structure in mortar in relation to aggregate content.” Cem. Concr. Res., 52(10), 149–160.
Hamada, M. (1968). “Neutralization (carbonation) of concrete and corrosion of reinforcing steel.” 5th Int. Symp. on Cement Chemistry, Cement Association of Japan, Tokyo, 343–369.
Houst, Y. F., and Wittmann, F. H. (1994). “Influence of porosity and water content on the diffusivity of and through hydrated cement past.” Cem. Concr. Res., 24(6), 1165–1176.
Huang, Q. H., et al. (2012). “Numerical analysis of the effect of coarse aggregate distribution on concrete carbonation.” Constr. Build. Mater., 37(3), 27–35.
Ji, Y. S. (2012). “Experimental research and mechanism analysis on semi-carbonation zone in concrete.” J. Build. Mater., 15(5), 624–628.
Jia, Y. D. (2010). “Research on carbonation characteristics of high volume mineral mixtures concrete.” Dissertation, Tsinghua Univ., Beijing.
Jiang, L. X., and Zhang, Y. (1999). “Analysis and calculation of the length of half-carbonated zone in concrete.” Ind. Constr., 29(1), 4–7.
Maghsoodi, V., and Ramezanianpour, A. (2009). “Effects of volumetric aggregate fraction on transport properties of concrete and mortar.” Arab. J. Sci. Eng., 34(2), 327.
Mahmoud, N., and Ahmad, E. (2015). “Investigating the effect of the cement paste and transition zone on strength development of concrete containing nanosilica and silica fume.” Mater. Des., 75(1), 174–183.
Mehta, P. K. (1986). Concrete: Structure, properties, and materials, Prentice-Hall, Englewood Cliffs, NJ.
Mondal, P., Shah, S. P., and Marks, L. D. (2008). “Nanoscale characterization of cementitious materials.” ACI Mater. J., 105(2), 174–179.
Morandeau, A., Thiery, M., and Dangla, P. (2014). “Investigation of the carbonation mechanism of CH and CSH in terms of kinetics, microstructure changes and moisture properties.”Cem. Concr. Res., 56(10), 153–170.
Parrott, L., and Killoh, D. (1989). “Carbonation in a 36-year-old in-situ concrete.” Cem. Concr. Res., 19(4), 649–656.
Rao, G. A., and Prasad, B. K. R. (2002). “Influence of the roughness of aggregate surface on the interface bond strength.” Cem. Concr. Res., 32(2), 253–257.
Scrivener, K. L. (1989). “The microstructure of concrete.” Mater. Sci. Concr., 3(2), 127–161.
Scrivener, K. L., and Pratt, P. L. (1983). “Characterization of Portland cement hydration by electron optical techniques.” MRS Proc., Cambridge University Press, Cambridge, U.K., 351.
Scrivener, K. L., and Pratt, P. L. (1984). “Backscattered electron images of polished cement sections in the scanning electron microscope.” Proc., 6th Int. Conf. Cement Microscopy, International Cement Microsocopy Association, NM, 145–55.
Thiery, M., Villain, G., Dangla, P., and Platret, G. (2007). “Investigation of the carbonation front shape on cementitious materials: Effects of the chemical kinetics.” Cem. Concr. Res., 37(7), 1047–1058.
Wang, P. M., Feng, S. X., and Liu, X. P. (2013). “Preparation of flat-polished specimens of cement paste for Backscattered Electron Imaging and Analysis.” J. Ceram. Soc., 41(2), 211–217.
Xiao, J. Z., Li, W. G., Sun, Z. H., Lange, D. A., and Shah, S. P. (2013). “Properties of interfacial transition zones in recycled aggregate concrete tested by nanoindentation.” Cem. Concr. Compos., 37(3), 276–292.
Yan, F., Jin, W. L., and Zhang, L. (1999). “Effect of semi-carbonation zone on concrete carbonation model.” Ind. Constr., 29(1), 12–16.
Zhang, J. K., Shi, C. J., and Li, Y. K. (2015). “Influence of carbonated recycled concrete aggregate on properties of cement mortar.” Constr. Build. Mater., 98(11), 1–7.
Zheng, J. J., and Zhou, X. Z. (2007). “Algorithm for the aggregate volume fraction threshold of interfacial transition zone percolation in concrete and evaluation of influencing factors.” J. Ceram. Soc., 35(10), 1342–1346.
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©2017 American Society of Civil Engineers.
History
Received: Jun 24, 2016
Accepted: Oct 19, 2016
Published online: Mar 2, 2017
Published ahead of print: Mar 16, 2017
Published in print: Jul 1, 2017
Discussion open until: Aug 2, 2017
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