Packed Bed Column for Adsorption of Arsenic on Mixed-Valent Iron [Fe(II)-Fe(III)] Oxide Synthesized from Industrial Waste
Publication: Journal of Hazardous, Toxic, and Radioactive Waste
Volume 24, Issue 2
Abstract
Hundreds of millions of people in the world regularly intake groundwater that has a high-risk arsenic level. In several parts of Asia, the arsenic concentration reaches up to , which is above the drinking water standards of the World Health Organization (). The present study discusses the arsenic removal from groundwater using a mixed-valent iron [Fe(II)-Fe(III)] oxide, commonly known as magnetite. Mixed-valent iron [Fe(II)-Fe(III)] oxide particles were synthesized from iron oxide waste that was obtained from the steel industry. Six column reactors were operated based on different operational variables, such as amount of adsorbent, particle size, initial arsenic concentration, empty bed contact time (EBCT), and flow rate. Four columns were continuously operated for 44 days, and two columns were operated for 80 days. The adsorption profile was maintained well for all the reactors with more than 98% arsenic removal efficiency from influent water. The shorter breakthrough curve was achieved for the columns operated with a higher influent arsenate concentration as compared with the columns operated with a low influent arsenate concentration. Moreover, the longer breakthrough curve was achieved for the column packed with a higher quantity of adsorbent. The column operated with a low EBCT and high flow rate resulted in the earlier breakthrough because arsenate ions did not get adequate time to bind at the adsorption sites and, subsequently, excited the column before it reached the state of equilibrium.
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Data Availability Statement
The data that support the findings of this study are available from the corresponding author upon reasonable request.
Acknowledgments
This work was supported by the Development of Eco-Smart Waterworks System Program of the Ministry of Environment, Korea (Project #: 2016002110009) and the Korea Research Fellowship Program through the National Research Foundation of Korea (NRF) funded by the Ministry of Science and ICT (Grant No. 2019H1D3A1A02071191).
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©2020 American Society of Civil Engineers.
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Received: Jun 6, 2019
Accepted: Sep 9, 2019
Published online: Jan 14, 2020
Published in print: Apr 1, 2020
Discussion open until: Jun 14, 2020
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